Yes. Two hours wasn't long enough...
When you turned the heating ON the room was either too hot or too cold. Ergo no heat or lots of, in the rad. If you'd left the heating on for longer (and also assuming the rads were all set up with the correct Delta T via the lockshield, as should've been the case but probably wasn't...) then as the room approached the setpoint of the TRV flow would have reduce and thus the Delta T across the rad.
The adjustment of a TRV to set room temperature is pretty subtle.