Thanks @Ferdinand
Your thread and @Jeremy Harris tip mentioned in it (re Unico units) has kept me busy of the day and lead to some more options that might work. All towards the upper end of the price range you mentioned though.
Turns out that the Olimpia Splendid Unico range includes a couple of options in addition to the single room model, with heat pumps, so usable for warming too. One with the option to feed a second unit up to 10m away (perhaps most useful in my case , for bedroom + living room), and another that heats a 50L DHW tank. All of them are based on through-wall-vents being one side of the wall with the aircon unit on the other, rather than having a air supply that can be ducted further. Although I guess I could probably duct them anyway if necessary, subject to adding a condensation trap and using smooth walled ducting.
http://zymbo.eu.url (Chinese made, Italian site, PDFs in English) also has several through-the-wall models. There's also Fimer's Windy range, different in that they they use a single hole though the wall with a pair of concentric pipes, though I'm not keen on their styling.
Finally, I also found Airwell GCAO, which has a water condenser, rather than using outside air. Consequently it can be located anywhere within range of a water supply, and can be connected to one or more remote wall or ceiling cooling units. On the downside, it only does cooling, and it also throws away hot(?) water - 90 litres / hour for the base model, if I've understood their data sheet properly - which I may not have, as it suggests the water is only at 15°C (page 6, English in the right hand column). I do wonder if I could turn that into a closed circuit by running the waste water though a DHW tank, and loosing excess heat though a heat exchanger in the MVHR extract duct, with some way of capping the aircon level to match, but there are probably several gaps in that idea, apart from the cost.
Anyway, further ideas are still very welcome.