Sounds like the hot water circuit might be gravity, how many pipes go to the multifuel? Or is the system "pumping over", with the pump forcing water out of the vent pipe and back into the F&E tank?
Are there any other pumps, like beside the oil boiler?
You might try as a first go, closing the valves on the hot radiators to force the flow to the others. Once you've flow to all than you can worry about balance...