A TS will best deal with the rads / Ufh mix, and you may want to improve that with a separate coil in the TS to supply heat to the rads. That'll enable you to isolate the Ufh and therefore not allow any ferrous particulate ( rust / corrosion ) to contaminate the Ufh and associate components. That would create a separate circuit which would require its own filling loop / PRV / and exp vessel but would ensure the water stayed clean in the Ufh system, which it wouldn't do in a conventional 'mixed' setup. Contamination in a mixed system can be managed with inhibitors and a good maintenance schedule, but will not remove all of the problem like isolating it would.
Consider slightly oversizing the rads and running them off an Ufh manifold to get the flow temp down so the rads run at a lower flow temp as you'll not want the rads running of the TS direct because then they'll be at the boiler flow temp which, with a TS, would be uncomfortably / unnecessarily hot in a well insulated house Running off an Ufh manifold will easily allow integration of individual room stats in each bedroom / space served by rads for total comfort control and will prevent any unoccupied spaces from getting heated when not required. I've done these setups before, exactly like this, and they work really well, just depends on how much control you do / don't want.