Rockwool is about half as thermally efficient as PIR, so would you need twice the thickness for the same insulation. Insulated plasterboard has either PIR or EPS. The EPS is between rockwool and PIR for performance.
If you have space you can build a new timber wall and insulate it.
It is good to have a grille between the gutter and the surface water sewer to trap leaves etc. No need for a trapped gulley. Rodding is never likely to be needed although you may get roots invading and it is best to have some access to deal with this.
I have had these fitted in some flats. They are quite clever. If you wire in a switched live they also look at how long the light is on to work out the overrun needed. Cheap too.
I have a 100A single phase supply and use it for the house and to supply a twin EV charge point that will supply 2 sockets up to 7.4kW each.
Some of the plug in hybrids have a very small battery / electric range so they may not be optimised for quicker home charging.
So internally insulated block cavity wall. Are the internal walls mostly timber stud (other than the brick one)? Do they go up after the insulation / battens?
BTW if you want someone to see you have mentioned them, type "@" and then pick their name from the drop down list @Gary Martin.
Yes it looks fine to do. There may not even be a lintel above the door, but better to put a new one in as you are altering the opening and the making good will be easier.
I would hoover out as much crap as I could then slide some pipe insulation down as far as it will go. That will stop the condensation. A bit naughty using gas ducting but it could be worse.