Sometimes I have had the sockets on a flex under the units. Quite a few appliances have moulded plugs and it may be that any warranty can be voided if you cut them off. It is not simple to anticipate what is needed. I have had induction hobs needing hard wiring on a separate circuit where others are plug in 13A.
I like under cupboard lights to be switched from an extra gang on the main light switch, which can also be a challenge.
You don't need to be qualified to build a house in the UK. ICF is fairly easy DIY. It would be more impressive if you built in brick and block.
No requirement for Gas Safe if it is just for you but would be my preferred option.
The Dritherm 32 slabs are easy for the bricklayer to fit, easy for wall ties, decent u-value, don't make a mess if the wall gets drilled and easy to clean up mortar droppings. EPS beads are good too but you said you are not keen on them.
Bear in mind that lots of EWI has been a disaster recently. Lots of mould, damp and ventilation issues, so this needs to be done meticulously, especially mixing EWI and IWI.
I think you may find it tricky to do much as you will need to drill / hammer to get any ties in and this will disturb the brickwork further. Maybe helical ties would work?
I think it may work well with either internal pir or insulated plasterboard, so move the 50mm celotex inside. It follows the rule of thumb of having the most insulating and vapour impermeable materials inboard.