It may be a bit late, but just commissioned a system similar to what you are looking at, here is what I have, after a few changes.
Atag combi boiler,
Telford thermal store (acting as a buffer with benefits) with boiler heating coil, DHW heating coil, mixing valve at outlet. Thermostat (middle of tank) set at 45 degrees, to reduce heat loss.
UFH running at 30 degrees
Solar PV
Hook up, cold water to DHW coil, this passes through TS, and into combi, if it is hot or cold, the Atag boiler is designed to take pre heated water, so boiler doesn't care, the boiler only puts the energy it needs to the correct outlet temp. Upside, if preheated, you get great hot water flow. In the summer solar PV should do a lot of preheat. Have a secondary circuit, pump with simple timer at the out DHW outlet, so it can pick up hot water from TS coil or pass through the combi.
Boiler was short cycling connected direct to UFH, so the UFH manifold now has mixer valve and pump added, this is connected direct to thermal store. Boiler connected direct to TS heating coil, boiler temp set at 50 degree.
Advantages, boiler is always in condensing mode. Simple hook up, low standing losses as the tank is no hotter than 45 to 50 degrees.