The rf controls are plug and play, with the windows addressable to open / close etc in tandem (or more) at the press of one button.
Not seen 24v options but I’ve not seen every model / iteration.
Velux tech should be able to give you concise information regarding which models / units can be manipulated the way you want them to be. Lots of options, so it may be advantageous to better understand what’s available so you can get the best results.