If they are quoting a buffer it isn't an expansion vessel.
A buffer requires secondary pumps, a volumiser doesn't. A buffer provides hydraulic seperation and therefore needs a pump(s) for the heating circuit.
Samsung Gen 7 schematic don't compel the use of a buffer, if your are doing an open system. They show a volumiser on the flow to heating circuit.
Cylinder size is basically worked out as follows, 45L per bedroom, plus 40L.
Reheat time assuming 300L and a 5kW output will be around 1hr and 20 mins to 50 degs, assuming bulk average temperature is about 30 degs.