I'm in the middle of converting my attic having recently moved in and having had pretty much the same plans as yourself.
My trusses were at 400mm centre having given no thought to roof windows, would have made life easier if I had at least looked up the standard widths and space a couple to suit. Get in double trusses too where they will be needed.
Watch for min max height of the lower openings if they are to be escape windows and also the distance down the roof the the eves, think its 1700mm max.
Check head room on landing at top of stairs if it's under the sloping ceiling. Where are the stairs going, make sure they are drawn up to ensure they fit etc.
I had our sparks run a pair of wires up for a ring for sockets, and supply for lighting.
MVHR ducts, rad pipes, smoke alarm wiring also all worth considering if you meed any of them.