Many thanks for the super suggestions - taken a number on board and attached a revision of the plant room plus included the ground floor plan to give a bit of context of positioning.
(still waiting for elevations from the architect so cant show those).
@PNAmble - sounds like our builds are quite similar! - our kitchen is also above the plant room. What are you doing for heating(UFH/radiators?) on each floor.
MVHR input/output placed on the same wall to keep air pressure equalised.
ASHP moved further East to allow space for MVHR intake. Positioning on the southern side is not an option (too close to the bedrooms), although it seems that there is no real noticeable difference in ambient air temperatures (locating on south side v north).
Unvented HWC (HWC) - moved close to the ASHP and run pipes in the space rather in a slab via a long duct - simpler and easier to change in the future should the need arise.
My initial thought was place the HWC as close as possible to the bath/showers in order to shorten pipe runs but energy expert Dave Hilton ( https://www.homebuilding.co.uk/advice/air-source-heat-pump-positioning ) maintains distance from the manifold/HWC is key.
A bit of conundrum, so going for a compromise and will place the manifold/HWC to be roughly equidistant between the ASAP and bath/showers.
Combined the two rooms into one room but retained an internal door - I think it feels better to keep the sink well away from the electrics.
Inverter - retained to be outside the thermal area - it is out of the sun and weather , my understanding is it will (hopefully) last a bit longer working in a cooler environment
and avoids having the extra heat internally in the summer.
Battery - retained internally, I get the concern over the potential fire hazard - in (hopefully never) event of a fire then it will kick off the fire alarm and the sprinklers which you will not get quite so easily if located on the outside wall.
Using Kiosk alongside the plant room is an interesting idea to reduce slab duct connections - will look into that.