Thanks Andy, the garage is the same construction as the rest of the house, a cavity wall with stone on the outside and blocks on the inside with that usual 1 inch of polystyrene insulation stuck on the blocks, so I think I might be OK. I think I'm going to add a layer of this stuff over the studs, it's cheap and has surprisingly good insulation values. I'll do the garage doors as well.
I've added the polystyrene boards into the calculation and it's now showing excellent thermal values but really poor moisture proofing, not sure if I should be worried about that as it's not an external wall?
Hall_Farm_with_polyboards (2).pdf