The first things I did when we moved in back in 2016 was double jacket the boiler lower the heating temp from 75 to 65 and insulate the loft space to 300mm
The arostor, edel options are the ones I am looking at now. It was suggested rather than one of those I look at a thermodynamic panel system. But there is even less information about them in the UK than the AIO heatpump options.
Loads of American reviews about the AIO systems but it's harder to translate that to how they would perform here.
The arostor and edel both have COP ratings of around 3 which would in theory cut my bill for heating water by 2/3rds.
The AIO option could be ducted from my living room (which in winter has the 5kw stove on 24/7 giving it warmer air to use and I could plumb the exhaust outside meaning I shouldn't see a large cooling effect from the AIO. The only issue there is where my existing tank is its right in the middle of the house and the AIO options are slightly noisy (I would combat that buy running during the day instead of at night)