Here are a couple of pictures to hopefully help explain what I am trying to do.
Bathroom is above porch and has three external walls.
Timber frame is made from 140x47mm timber, currently has 100mm of rockwool in the wall, Would like to improve insulation while I have the plasterboard off but not sure what would be best.
External surface seems to render on ply with a waterproof membrane between the ply and timber frame.
House was built in 1987 so not sure what the membrane (sorry if that is wrong word) is. It isn't roofing felt. Forgot to take a photo of it.